Iimveliso
I-Dibenso-18-Crown-6; I-CASS.1872-7-7
Izithethantonye: I-Dibenso-18-Crown-6; Polyteer Xxviiiii
Ipropathi yamachiza e-Dibenzo-18-Crown-6
● Inkangeleko / umbala: White ukuya kwi-boly beige powder
● Uxinzelelo lwe-vapor: 3.65E-10mmhg nge-25 ° C
● Indawo yokunyibilika: 162-164 ° C (ikhanyisiwe.)
● Isalathiso seNgxelo yeNgxelo: 1.5
● Inqaku lokubila: 503.1 ° C nge-760 mmhg
● Inqaku leFlash: 206 ° C
● psa:I-55.38000
● Ukuxinana: 1.108 g / cm3
● I-Logp: 2.94880
● Indawo yokugcina indawo.
● Ngokutsho
● Ukuzalelwa.:0.007g/l
● Ukuzola amanzi
● I-XlogP3: 2.2
● I-Hydrogen Bop Count Count: 0
● Ubalo lwe-Hydrogen Bopptor: 6
● Ibhondi enzobiziweyo: 0
● Ubunzima obuthe ngqo: 360.15728848
● Ukubalwa kweatom enzima: 26
● Ukuntsonkotha: 300
Ulwazi olukhuselekileyo
● I-pictogram (s):
Xi,
Xn
● Iikhowudi zengozi: xi, xn
● Iingxelo: 36-36 / 38/8-20 / 21/22
● Iingxelo zoKhuseleko: 26-37 / 39-36
Iluncedo
Iiklasi zekhemikhali:Ezinye Iiklasi -> Ezinye izinto eziLungelelani
I-Canonical iyancuma:I-C1COC2 = cc = cc = c2occoccoc3 = cc = cc = c3Occo1
IISEBE:I-Dibenso-18-Crown-6, isetyenziswa njengezixhobo ezibalulekileyo eziluhlaza kwaye zisetyenziswe kwi-ornthesic synthesi, amayeza, i-agrochemicals kunye neDystuff. Sisiseko esibalulekileyo se-organic. Isithsaba I-Ether / Dibenso-18-Crown-6 yeSynthesis. I-14187222-7, ubunzima be-molar 360.41 g / mol.
Intshayelelo Eneenkcukacha
I-Dibenzo-18-Crown-6, ekwabizwa ngokuba yi-DB18C6, kukuphazamiseka kwe-18-crown-6 equlethe amakhonkco amabini e-Bezene aqhotyoshelwe kwisithsaba se-thy. Yinxalenye ye-ether ye-cyclic ye-cyclic ye-chemic fomall fomac c0h24o6. Ukongezwa kwamakhonkco e-Dezene ukuya kwi-18-Crown-6 kuphucula uzinzo lwayo kwaye kuguqula iipropathi zayo, ukwenza i-DIBENZO-18-Crown-6 i-6 inqaku elahlukileyo.
Ubukho bamakhonkco e-Bezene e-Dibenso-18-Crown-6 wazisa ubusela kwimolekyuli, enokuba nefuthe elikhulu kwimichiza. Ukongezwa kwezi rings kuphucula i-Electron kwimousekokhwe, ukwenza i-DIBENZO-18-Crown-6 engaguquli ngokuthelekiswa nomzali ongumzali, i-18-crown-6.
Ukuqaliswa kweMoietic Momatic eDibenso-18-Crown-6 nayo iguqula ukunyibilikisa kunye nobubele. Olu tshintsho luhlala lukhokelela ekuphuculeni ukuqina kwezinyibilikisi eziphilayo, zenza uDibenso-18-Crown-6 ilungele iindlela ezahlukeneyo ezifuna ukuchithwa kwayo kwi-on-polar okanye kwi-armatic senvent.
Ngokufana ne-18-Crown-6, i-Dibenso-18-Crown-6 igcina amandla okubaleka ii-ion zentsimbi, ezenza uzinzo oluzinzileyo. Ubukho bamakhonkco ama-Benzene bunokuphucula ngakumbi ukukhetha kunye nokuzinza kwezi zentsimbi, ukwenza uDibenso-18-Crown-6 luncedo, kunye ne-cataissis, efana nomzali ohlanganisiweyo.
I-DIBENZO-18-Crown-I-6-I-Crogal-6 ephuculweyo kunye nozinzo zikwenza ukuba ixhathise ngakumbi kwi-Debradiyation Patlet Litch kwi-18-Crown-6. Eli nqaku linegalelo kwisicelo sayo ngokujonga ubushushu obuphezulu kunye neenkqubo.
Ngelixa i-Dibenso-18-Crown-6 Yabelana ngezinto ezifanayo ne-18-Crown-6, iipropathi zayo ezahlukileyo zenza ukuba zibe yingqungquthela eyahlukeneyo kwi-chemistry, i-Solvent Shortment, kunye neenkqubo zobushushu eziphakamileyo. Ukongezwa kwamakhonkco e-Benzene ukuya kwi-Frown Grown Grown Ather Superications kuphucula iimpawu zalo zonyibiliko, kwaye kwandise ukusetyenziswa kwayo kwiindawo ezahlukeneyo ze-chemistry kunye nesayensi yezixhobo.
Isicelo
I-Dibenso-18-Crown-6 (DB18C6) ineendlela ezahlukeneyo kwimimandla eyahlukeneyo, kubandakanya:
Ukukhutshwa kwentsimbi kunye nokwahlukana:I-DB18C6 isebenza kakhulu ekusokola ii-ion zentsimbi. Isakhono sayo sokukhetha ukubopha nge-ion yentsimbi efana nesodium, i-potassium, kunye ne-Amonium yenza ukuba iluncedo kwi-ion yentsimbi kunye neenkqubo zokwahlukana. Inokuqeshwa kwiindlela zokukhuthaza ukuqinisa ngokukhetha ii-ions ezithile zentsimbi kumxube.
I-chemistry yodidi:I-DB18C6 isetyenziswe ngokubanzi kwiChempmmolecular chemistry. Isakhiwo sayo esikhethekileyo senze ukuba ilungele ukubekwa ziindwendwe ezimamkeli ngeemolekyuli ezahlukeneyo, kubandakanya iziko lezinto ezincinci zezinto eziphilayo kunye nee-ion zentsimbi. Ezi ngxaki ze-Hust-Guest zinokusetyenziselwa uyilo nolwakhiwo lweenkqubo zemolekyuli ezisebenzayo kunye nezixhobo.
I-ion ivele:Ngenxa yesithsaba sayo esithwele i-thrown, i-DB18C6 inokukhetha ukubopha nge-ion ethile, ekhokelela kutshintsho kwi-ofisi yayo, i-elektrochemical, okanye iipropathi zefayili. Le propati yenza i-DB18c6 i-ion yexabiso elixabisekileyo ye-ion, enokuqeshwa kuphuhliso lwazo oosoyeza kunye nabacimi.
I-Catalysis:I-DB18C6 kwaye i-ion yayo yentsimbi inokusebenza njenge-catalysts zokuphendula ezahlukeneyo. Izakhiwo zabo ezizodwa zibonelela ngendawo efanelekileyo yokuqhubela phambili utshintsho oluthile lwemichiza. I-Catalysts esekwe kwi-DB18C iqeshwe kwi-orntaic synthesis synthesi, yokuphendula kwe-oxidation, kunye nezinye iinkqubo zengozi.
Iinkqubo zobushushu eziPhezulu: Uzinzo oluphuculweyo kunye nokuxhathisa ukonakala kwe-DB18C Ingasetyenziselwa ukuphendula okunezisindo okuphezulu, kubandakanya i-polymerization, i-ornthesic synthesis, kunye nezinye iinkqubo zobushushu obuphakamileyo.
Iinkqubo zeSolvent: Njengoko bekutshiwo ngaphambili, ukungeniswa kwamakhonkco e-Benzene kwi-DB18C6 kuphucula iindlela zayo kwi-orlar okanye kwiinkqubo ze-onvent. Le ndawo iyenza ukuba idibaniso eliluncedo kwizicelo ezifuna ukuchithwa kwayo kwiindawo ezithile zeSicolve.
Ngokubanzi, ubume obukhethekileyo kunye neepropathi ze-DB18C6 Yenza uluhlu olubanzi lwezicelo kulungelelaniso lwe-chemistry, cheramolecular chemistry, i-ions, kunye neenkqubo zobushushu eziphakamileyo. Ukukwazi kwayo ukukhetha ukunxibelelana neemolekyuli ezahlukeneyo kunye nee-ion zentsimbi kwenza ukuba kube yindawo ebaluleke kakhulu kuphando kunye nemimandla yemizi-mveliso.
